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2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate

2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate

CAS: 21282-97-3

Molecular Formula: C10H14O5

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2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate - Names and Identifiers

Name 2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate
Synonyms AAEM
Monomer AAEMA
2-(METHACRYLOYLOXY)E
ACETOACETOXYETHYL METHACRYLATE
2-(Acetoacetoxy)ethyl methacrylate
ACETOACETOXY ETHYL 2-METHYLACRYLATE
2-(Methacryloyloxy)ethyl acetoacetate
2-[(2-methylacryloyl)oxy]ethyl 3-oxobutanoate
2-((2-Methyl-1-oxoallyl)oxy)ethyl acetoacetate
2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate
ACETOACETIC ACID 2-(METHACRYLOYLOXY)ETHYL ESTER
3-oxo-butanoicaci2-[(2-methyl-1-oxo-2-propenyl)oxy]ethylester
Butanoic acid, 3-oxo-, 2-((2-methyl-1-oxo-2-propenyl)oxy)ethyl ester
Butanoic acid, 3-oxo-, 2-((2-methyl-1-oxo-2-propen-1-yl)oxy)ethyl ester
2-(Methacryloyloxy)ethyl acetoacetate,(2-Acetoacetoxy)ethyl methacrylate, AAEM, Ethylene glycol monoacetoacetate monomethacrylate, Lonzamon AAMEA PQ
CAS 21282-97-3
EINECS 244-311-1
InChI InChI=1/C6H10O3.C4H6O3/c1-3-5(7)4(2)6(8)9;1-3(5)2-4(6)7/h7H,3H2,1-2H3,(H,8,9);2H2,1H3,(H,6,7)/p-2/b5-4+

2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate - Physico-chemical Properties

Molecular FormulaC10H14O5
Molar Mass214.22
Density1.122 g/mL at 25 °C (lit.)
Boling Point100 °C/0.8 mmHg (lit.)
Flash Point>230°F
Water Solubility18.5g/L at 25℃
Solubility Insoluble in water
Vapor Presure0.24Pa at 25℃
Appearanceclear liquid
Specific Gravity1.122
ColorLight yellow to Yellow to Orange
BRN2099809
pKa10.16±0.46(Predicted)
Refractive Indexn20/D 1.456

2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate - Risk and Safety

Risk CodesR36/37/38 - Irritating to eyes, respiratory system and skin.
R43 - May cause sensitization by skin contact
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36 - Wear suitable protective clothing.
UN IDsUN 2810 6.1/PG 3
WGK Germany3
RTECSAK5600000
HS Code29189990

2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate - Reference Information

LogP0.9 at 25℃
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Use The main features for low VOC solvent-based coating resin, so that its viscosity is reduced. Improves the elasticity and toughness of the coating, reduces the glass transition temperature for excellent elasticity and corrosion resistance. Reaction with commonly used cross-linking agents, such as melamine (melamine) and isocyanates. Film formation at room temperature, no isocyanate cross-linking, through the Meckel reaction, the enamine structure can react with aldehydes and hydrazide. The adhesion to the metal layer is improved by the interaction of AO and metal ions. Excellent adhesion ability in humid environment acetoacetylated polymer pesticide intermediate high-solid acrylic resin solution reactive monomer cross-linking agent for Photocuring polymer for cosmetics polymer pharmaceutical intermediate self-crosslinking acrylic emulsion can replace N-methylolacrylamide, diacetone acrylamide, HEMA, etc., with better reaction control and better product performance
Last Update:2024-04-09 21:01:54
2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate
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View History
2-[(2-methyl-1-oxoallyl)oxy]ethyl acetoacetate
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